First you have to download Matrikon OPC Explorer from http://www.matrikonopc.es/products/opc-desktop-tools/opc-explorer.aspx
Once installed, execute it and try to browse your Arduino OPC Server.
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If Arduino OPC Server is not shown then maybe you need to configure Matrikon OPC Server to find it.
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Go to Options and configure Matrikon OPC Server to search for OPC Servers from the Windows registry.
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Now you can connect to your OPC Server for Arduino. Remember to configure it adding your Arduino communication COM Port.
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The OPC Server will be launched and will start communicate with your Arduino. Now you can create your items groups.
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Now you have created your “test” group and now you should add OPC Items to it.
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Press right click mouse to get the popup menu to “Add All Items to Tag List” or select only the Items you want.
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Now you should get all your OPC Items from your Arduino in real time 🙂